You are surely free to print the e-book but be advised that e-book has been formatted for easy on screen reading and is different from the preview of print book shown on the website. To get a good looking printed book, order a copy by clicking on "Buy Printed Copy" button and following the instructions.
The differences between Print ready files and e-books are given below. Print ready files will:
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Use a font suitable for reading a printed book (usually a serif font for English content)
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Possibly have blank pages, when new section starts in the book to ensure that the new section starts on an odd page (right side of the book).
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Have URLs separated out from anchor text, as there is no concept of clickable links in print!
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Have separate Interior and Cover files because that's how they will be printed finally.
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Other optimizations for making the content look good in print
On the other hand, e-books will:
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Use a font suitable for reading on screen
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Have clickable URLs, whenever it is so in original content
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Have cover and interior together in the same file